Ruthenium-catalyzed hydrovinylation of N-acetylenamines leading to amines with a quaternary carbon center.
نویسندگان
چکیده
A catalytic hydrovinylation of N-acetylenamines with ethylene is reported. This new hydrovinylation reaction is catalyzed by a ruthenium hydride complex, RuHCl(CO)(PCy(3))(2), providing a series of N-acetylamines with a quaternary carbon center with up to 99% yield.
منابع مشابه
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ورودعنوان ژورنال:
- Organic letters
دوره 13 13 شماره
صفحات -
تاریخ انتشار 2011